Numerical Investigation of Heat and Mass Transfer Processes while the Desorption of Hydrogen Gas Stored in MmNi4.6Fe0.4-H6

Ali Boukhari

Abstract

This work presents a numerical investigation of two-dimensional coupled heat and mass transfer processes in a unit disc of an annulus-disc reactor filled with the intermetallic (Mischmetal) compound MmNi4.6Fe0.4, during the hydrogen gas desorption using the finite volume method. Temperature and amount of desorbed hydrogen and their time-averaged quantities inside the metal hydride bed are presented for different heat transfer fluid temperatures, and different metal thermal conductivities. Impacts of both effects on the metal hydride reactor performance in terms of discharging time are examined by means of a set of numerical simulations. Thus, the dehydriding time minimization relates to the adjustment of the amount of heat addition to the packed bed reactor. A good agreement was found between the present computational results and the experimental data reported in the literature.

Full Text:

PDF

References

L. K. Heung, “Using metal hydride to store hydrogen,” DOE report, WSRC-MS-2003-00172, 2003.

A. Isselhorst, “Heat and mass transfer in coupled hydride reaction beds,” J. Alloys Compounds, vol. 231, pp. 871-79,

K. Aldas, M. D. Mat and Y. Kaplan, “A three-dimensional mathematical model for hydrogen absorption in a metal

hydride bed,” Int. J. Hydrogen Energy, vol. 27, pp. 1049-56, 2002.

P. Marty, J. F. Fourmigue, P. De Rango, D. Fruchart and J. Charbonnier, “Numerical simulation of heat and mass

transfer during the absorption of hydrogen in a magnesium hydride,” Energy Conversion and Management, vol. 47, pp.

-43, 2006.

A. K. Phate, P. Maiya and S. Murthy, “Simulation of transient heat and mass transfer during hydrogen sorption in

cylindrical metal hydride beds,” Int. J. Hydrogen Energy, vol. 32, pp. 1969-81, 2007.

R. Gopal and S. Murthy, “Prediction of heat and mass transfer in annular cylindrical metal hydride beds,” Int. J.

Hydrogen Energy, vol. 17, pp. 795-805, 1992.

H. Choi and A. F. Mills, “Heat and mass transfer in metal hydride beds for heat pump applications,” Int. J. Heat and

Mass Transfer, vol. 33, pp. 1281-89, 1990.

A. Boukhari and R. Bessaïh, “Numerical heat and mass transfer investigation of hydrogen absorption in an annulusdisc

reactor”, Int. J. Hydrogen Energy, vol. 40(39), pp. 13708-17, 2015.

D. Chabane, F. Harel, A. Djerdir, M. Ibrahim, D. Candusso, O. Elkedim and N. Fenineche, “Influence of the key

parameters on the dynamic behavior of the hydrogen absorption by LaNi5”, Int. J. Hydrogen Energy, (Article in

press), 2016.

I. A. El-Osery, M. A. El-Osairy, A. M. Metwally, M. M. Keshk and M. El-Gammal, “Dynamic simulation of the

convective model for metal hydride hydrogen storage beds,” Energy Sources, vol. 15, pp. 523-30, 1993.

A. Demircan, M. Demiralp, Y. Kaplan, M. D. Mat and T. N. Veziroglu, “Experimental and theoretical analysis of H2

absorption in LaNi5-H2 reactors,” Int. J. Hydrogen Energy, vol. 30, pp. 1437-46, 2005.

E. Kikkinides, M. Georiadis and A. Stubos, “On the optimization of hydrogen storage in metal hydride beds,” Int. J.

Hydrogen Energy, vol. 31, pp. 737–51, 2006.

A. Dogan, Y. Kaplan and T. N. Veziroglu, “Numerical investigation of heat and mass transfer in a metal hydride bed,”

App. Math. and Computation, vol. 150, pp. 169-80, 2004.

B. MacDonald and A. Rowe, “Impacts of external heat transfer enhancements on metal hydride storage tanks,” Int. J.

Hydrogen Energy, vol. 31, pp. 1721-31, 2006.

D. P. Broom, Hydrogen storage materials: The characterization of their storage properties, Springer-Verlag London,

M. Visaria and I. Mudawar, “Experimental investigation and theoretical modeling of dehydriding process in highpressure

metal hydride hydrogen storage systems,” Int. J. Hydrogen Energy, vol. 37, pp. 5735-49, 2012.

G. Mohan, P. Maiya and S. Murthy, “Performance simulation of metal hydride hydrogen storage device with

embedded filters and heat exchanger tubes,” Int. J. Hydrogen Energy, vol. 32, pp. 4978-87, 2007.

C. A. Krokos, D. Nikolic, E. S. Kikkinides, M. C. Georgiadis and A. K. Stubos, “Modelling and optimization of multitubular

metal hydride beds for efficient hydrogen storage,” Int. J. Hydrogen Energy, vol. 34, pp. 9128-40, 2009.

A. Freni, F. Cipiti and G. Cacciola, “Finite element-based simulation of a metal hydride-based hydrogen storage

tank,” Int. J. Hydrogen Energy, vol. 34, pp. 8574-82, 2009.

F. Yang, X. Meng, J. Deng, Y. Wang and Z. Zhang, “Identifying heat and mass transfer characteristics of metal

hydride reactor during adsorption- parameter analysis and numerical study,” Int. J. Hydrogen Energy, vol. 33, pp.

-22, 2008.

A. Bejan and A. D. Kraus, Heat Transfer Handbook, John Wiley & Sons, Inc, 2003.

A. Jemni, S. Ben Nasrallah and J. Lamloumi, “Experimental and theoretical study of a metal–hydrogen reactor,” Int. J.

Hydrogen Energy, vol. 24, pp. 631-44, 1999.

G. Sandrock and G. Thomas, IEA/DOE/SNL Hydride Databases, [Online available] http://hydpark.ca.sandia.gov.

H. K. Versteeg and W. Malalasekera, An Introduction to Computational Fluid Dynamics: the finite volume method,

nd Edition, Pearson Education Ltd, 2007.

Open∇ FOAM, The Open Source CFD Toolbox User Guide, Version v1606+, OpenCFD Ltd, 2016.

Refbacks

  • There are currently no refbacks.